Tuning the Spin States of Two Apical Iron(II) Ions in a Pentanuclear Iron(II) Cluster Helicate through the Choice of Anions
Spin-crossover clusters with iron(II) high nuclearity are rare. By using 3,5-bis(pyridin-2-yl)-1,2,4-triazole (bptH) as the ligand with two bidentate chelating sites, we successfully obtained three pentanuclear iron(II) cluster helicate compounds [{FeII(μ-bpt)3}2FeII3(μ3-O)][FeII2(μ-Br)(μ-bpt)(NCS)4...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2018-03-01
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| Series: | Crystals |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4352/8/3/119 |