Thermal Properties of Zeolite-Containing Composites

A zeolite (mordenite)–pore–phenol resin composite and a zeolite–pore–shirasu glass composite were fabricated by hot-pressing. Their thermal conductivities were measured by a laser flash method to determine the thermal conductivity of the monolithic zeolite with the proposed mixing rule. The analysis...

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Bibliographic Details
Main Authors: Taro Shimonosono, Yoshihiro Hirata, Kyohei Nishikawa, Soichiro Sameshima, Kenichi Sodeyama, Takuro Masunaga, Yukio Yoshimura
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/11/3/420
Description
Summary:A zeolite (mordenite)–pore–phenol resin composite and a zeolite–pore–shirasu glass composite were fabricated by hot-pressing. Their thermal conductivities were measured by a laser flash method to determine the thermal conductivity of the monolithic zeolite with the proposed mixing rule. The analysis using composites is useful for a zeolite powder with no sinterability to clarify its thermal properties. At a low porosity <20%, the thermal conductivity of the composite was in excellent agreement with the calculated value for the structure with phenol resin or shirasu glass continuous phase. At a higher porosity above 40%, the measured value approached the calculated value for the structure with pore continuous phase. The thermal conductivity of the monolithic mordenite was evaluated to be 3.63 W/mK and 1.70–2.07 W/mK at room temperature for the zeolite–pore–phenol resin composite and the zeolite–pore–shirasu glass composite, respectively. The analyzed thermal conductivities of monolithic mordenite showed a minimum value of 1.23 W/mK at 400 °C and increased to 2.51 W/mK at 800 °C.
ISSN:1996-1944