Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence

Intramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ∼1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents.

Bibliographic Details
Main Authors: Joo Taiha, Rhee Y. H., Im D., Young Kim So, Park Myeongkee
Format: Article
Language:English
Published: EDP Sciences 2013-03-01
Series:EPJ Web of Conferences
Online Access:http://dx.doi.org/10.1051/epjconf/20134105023