Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence
Intramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ∼1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents.
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
EDP Sciences
2013-03-01
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Series: | EPJ Web of Conferences |
Online Access: | http://dx.doi.org/10.1051/epjconf/20134105023 |