Determination of protonation constants and structural correlations for some tertiary formamides and acetamides in sulfuric acid with UV spectroscopy
The protonation of ten aliphatic amides in sulfuric acid media was studied by UV spectroscopy. The pKBH+ values and solvation parameters were calculated using Yates and McClelland Method, Excess Acidity Method and Bunnett and Olsen Method. pKBH+ values were –1.44, –1.15, –0.80, –0.32, –1.13 and –0.8...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Society of Chemists and Technologists of Macedonia
2015-11-01
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Series: | Macedonian Journal of Chemistry and Chemical Engineering |
Subjects: | |
Online Access: | https://mjcce.org.mk/index.php/MJCCE/article/view/702 |