Determination of protonation constants and structural correlations for some tertiary formamides and acetamides in sulfuric acid with UV spectroscopy

The protonation of ten aliphatic amides in sulfuric acid media was studied by UV spectroscopy. The pKBH+ values and solvation parameters were calculated using Yates and McClelland Method, Excess Acidity Method and Bunnett and Olsen Method. pKBH+ values were –1.44, –1.15, –0.80, –0.32, –1.13 and –0.8...

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Bibliographic Details
Main Authors: Goran Stojković, Elizabeta Dimitrieska-Stojković, Emil Popovski
Format: Article
Language:English
Published: Society of Chemists and Technologists of Macedonia 2015-11-01
Series:Macedonian Journal of Chemistry and Chemical Engineering
Subjects:
Online Access:https://mjcce.org.mk/index.php/MJCCE/article/view/702