Confinement Effects on Chemical Equilibria: Pentacyano(Pyrazine)Ferrate(II) Stability Changes within Nanosized Droplets of Water

Confinement Effects on Chemical Equilibria: Pentacyano(Pyrazine)Ferrate(II) Stability Changes within Nanosized Droplets of Water

Nanoscale confinement is known to impact properties of molecules and we observed changes in the reactivity of an iron coordination complex, pentacyano(pyrazine)ferrate(II). The confinement of two coordination complexes in a sodium AOT/isooctane reverse micellar (RM) water droplet was found to dramat...

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Bibliographic Details
Main Authors: Teofilo Borunda, Alexander J. Myers, J. Mary Fisher, Debbie C. Crans, Michael D. Johnson
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Molecules
Subjects:
Confinement effects
coordination chemistry at the nanoscale
pentacyano(pyrazine)ferrate(II)
[Fe(CN)5pyz]3−
hydrolysis rates
monomer-dimer equilibrium
reverse micelles
interface interactions
Online Access:http://www.mdpi.com/1420-3049/23/4/858

Internet

http://www.mdpi.com/1420-3049/23/4/858

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