Stereocontrolled eliminacion-cyclization of (+)-hanphylline
The reactions of stereocontrolled 1,5-cyclization of E, E-hermacrane hanphylline are studied. Cis-guaianolides is as a result synthesized. The mechanism of 1,5- carbocyclization is considered and the chart of biogenetic intercommunication of guaianolides is offered in Achillea nobilis L.
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
al-Farabi Kazakh National University
2012-12-01
|
| Series: | Chemical Bulletin of Kazakh National University |
| Online Access: | https://bulletin.chemistry.kz/index.php/kaznu/article/view/409 |