C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni(II) complexes with chlorophosphines
This manuscript reports successful C-H nickellation of the aryl phosphinites (i-Pr2P(O-aryl) derived from un-substituted/substituted phenols: C6H5OH, 4-R-C6H4OH (R = F, MeO). Nickellation was observed with the phosphinites at an ortho-C-H position to generate Br-bridged dimers [{κP,κC-(i-Pr)2PO-aryl...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
Elsevier
2021-02-01
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Series: | Journal of Saudi Chemical Society |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S1319610320301678 |