A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization

A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization

The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.

Bibliographic Details
Main Authors: Yusuke Hibi, Makoto Ouchi, Mitsuo Sawamoto
Format: Article
Language:English
Published: Nature Publishing Group 2016-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms11064
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spelling doaj-adb05ec269384e26887e8eee9d8579f92021-05-11T11:18:42ZengNature Publishing GroupNature Communications2041-17232016-03-01711910.1038/ncomms11064A strategy for sequence control in vinyl polymers via iterative controlled radical cyclizationYusuke Hibi0Makoto Ouchi1Mitsuo Sawamoto2Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-kuDepartment of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-kuDepartment of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-kuThe ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.https://doi.org/10.1038/ncomms11064
collection DOAJ
language English
format Article
sources DOAJ
author Yusuke Hibi
Makoto Ouchi
Mitsuo Sawamoto
spellingShingle Yusuke Hibi
Makoto Ouchi
Mitsuo Sawamoto
A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
Nature Communications
author_facet Yusuke Hibi
Makoto Ouchi
Mitsuo Sawamoto
author_sort Yusuke Hibi
title A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_short A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_full A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_fullStr A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_full_unstemmed A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_sort strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2016-03-01
description The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.
url https://doi.org/10.1038/ncomms11064
work_keys_str_mv AT yusukehibi astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT makotoouchi astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT mitsuosawamoto astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT yusukehibi strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT makotoouchi strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT mitsuosawamoto strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
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