A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2016-03-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms11064 |