Two-phase equilibrium states in individual Cu–Ni nanoparticles: size, depletion and hysteresis effects
In isolated bimetallic nanoscale systems the limit amount of matter and surface-induced size effects can change the thermodynamics of first-order phase transformation. In this paper we present theoretical modification of Gibbs free energy concept describing first-order phase transformation of binary...
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2015-08-01
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| Series: | Beilstein Journal of Nanotechnology |
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| Online Access: | https://doi.org/10.3762/bjnano.6.185 |
