Two-phase equilibrium states in individual Cu–Ni nanoparticles: size, depletion and hysteresis effects

Two-phase equilibrium states in individual Cu–Ni nanoparticles: size, depletion and hysteresis effects

In isolated bimetallic nanoscale systems the limit amount of matter and surface-induced size effects can change the thermodynamics of first-order phase transformation. In this paper we present theoretical modification of Gibbs free energy concept describing first-order phase transformation of binary...

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Bibliographic Details
Main Author: Aram S. Shirinyan
Format: Article
Language:English
Published: Beilstein-Institut 2015-08-01
Series:Beilstein Journal of Nanotechnology
Subjects:
chemical depletion
nanomelting and nanosolidification loops
phase diagram of isolated nanoparticle
surface-induced size effect
thermodynamic approach
Online Access:https://doi.org/10.3762/bjnano.6.185

Internet

https://doi.org/10.3762/bjnano.6.185

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