Crystal structure of potassium sodium heptahydrogen hexamolybdocobaltate(III) octahydrate: an extra-protonated B-series Anderson-type heteropolyoxidometalate

Crystal structure of potassium sodium heptahydrogen hexamolybdocobaltate(III) octahydrate: an extra-protonated B-series Anderson-type heteropolyoxidometalate

The title compound, KNa[CoIII(OH)7{Mo6O17}]·8H2O, was obtained by the ion-exchange technique from K3[Co(μ3-OH)6Mo6O18]·7H2O. Six μ3-O atoms and one O atom of the bridging μ2-O atom are protonated. This novel polyanion protonated by an extra H atom is an unexpected polyanion species among the B-serie...

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Bibliographic Details
Main Authors: Ki-Min Park, Hea-Chung Joo, Uk Lee
Format: Article
Language:English
Published: International Union of Crystallography 2015-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
novel protonated B series Anderson-type polyanion
hexamolybdocobaltate(III)
noncentrosymmetric strong hydrogen bond
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015014784

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http://scripts.iucr.org/cgi-bin/paper?S2056989015014784

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