Syntheses and crystal structures of 2-methyl-1,1,2,3,3-pentaphenyl-2-silapropane and 2-methyl-1,1,3,3-tetraphenyl-2-silapropan-2-ol

Syntheses and crystal structures of 2-methyl-1,1,2,3,3-pentaphenyl-2-silapropane and 2-methyl-1,1,3,3-tetraphenyl-2-silapropan-2-ol

The sterically hindered silicon compound 2-methyl-1,1,2,3,3-pentaphenyl-2-silapropane, C33H30Si (I), was prepared via the reaction of two equivalents of diphenylmethyllithium (benzhydryllithium) and dichloromethylphenylsilane. This bisbenzhydryl-substituted silicon compound was then reacted with tri...

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Bibliographic Details
Main Authors: Alexandra Williams, Michelle Brown, Richard J. Staples, Shannon M. Biros, William R. Winchester
Format: Article
Language:English
Published: International Union of Crystallography 2019-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
silanol
steric hindrance
diphenylmethyl
benzhydryl
O—H...π interaction
C—H...π interaction
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019011265

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http://scripts.iucr.org/cgi-bin/paper?S2056989019011265

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