Structural and Electronic Properties of Polyoxovanadoborates Containing the [V12B18O60] Core in Different Mixed Valence States

Structural and Electronic Properties of Polyoxovanadoborates Containing the [V12B18O60] Core in Different Mixed Valence States

This review summarizes all published data until April 2015 related to crystalline lattices formed by the [V12B18O60] core, which generates polyanionic clusters with different degrees of protonation and mixed-valence ratios. The negative charge of this cluster is counterbalanced by different cations...

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Bibliographic Details
Main Authors: Patricio Hermosilla-Ibáñez, Karina Muñoz-Becerra, Verónica Paredes-García, Eric Le Fur, Evgenia Spodine, Diego Venegas-Yazigi
Format: Article
Language:English
Published: MDPI AG 2015-07-01
Series:Inorganics
Subjects:
[V12B18O60]
polyoxovanadoborate
VBO
electronic properties
FT-IR
reflectance UV-vis
magnetic behavior
Online Access:http://www.mdpi.com/2304-6740/3/3/309

Internet

http://www.mdpi.com/2304-6740/3/3/309

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