Copper, Boron and Vinyl Epoxides: from 1,4-Diols to Cyclopropylboronates
Herein we describe the reactivity found between vinyl epoxides and catalytically generated copper-boryl complexes. By tuning the substituents of the alkene and/or the reaction conditions, 1,4-diols, allylic alcohols or cyclopropylboronates can be prepared. The stereochemical information of the vinyl...
Main Authors: | , , , |
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Format: | Article |
Language: | deu |
Published: |
Swiss Chemical Society
2020-11-01
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Series: | CHIMIA |
Subjects: | |
Online Access: | https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000011/art00002 |