Copper, Boron and Vinyl Epoxides: from 1,4-Diols to Cyclopropylboronates

Herein we describe the reactivity found between vinyl epoxides and catalytically generated copper-boryl complexes. By tuning the substituents of the alkene and/or the reaction conditions, 1,4-diols, allylic alcohols or cyclopropylboronates can be prepared. The stereochemical information of the vinyl...

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Bibliographic Details
Main Authors: Luis Novoa, Laura Trulli, Alejando Parra, Mariola Tortosa
Format: Article
Language:deu
Published: Swiss Chemical Society 2020-11-01
Series:CHIMIA
Subjects:
Online Access:https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000011/art00002