Manganese-catalyzed aziridination of olefins with chloramine-T in water and buffered aqueous solutions
A water-soluble, manganese-porphyrin complex was used to catalytically generate aziridines from olefins in moderate to good yields (up to 93%) upon optimization at room temperature and in aqueous media. Reactions using chloramine-T at slightly acidic to neutral pH values showed generally higher cata...
Main Authors: | Daniel K. Wolgemuth, Sydnee D. Elmore, James D. Cope, Patrick E. Sheridan, Sean L. Stokes, Joseph P. Emerson |
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Format: | Article |
Language: | English |
Published: |
Elsevier
2021-02-01
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Series: | Catalysis Communications |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736720303514 |
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