Manganese-catalyzed aziridination of olefins with chloramine-T in water and buffered aqueous solutions

A water-soluble, manganese-porphyrin complex was used to catalytically generate aziridines from olefins in moderate to good yields (up to 93%) upon optimization at room temperature and in aqueous media. Reactions using chloramine-T at slightly acidic to neutral pH values showed generally higher cata...

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Bibliographic Details
Main Authors: Daniel K. Wolgemuth, Sydnee D. Elmore, James D. Cope, Patrick E. Sheridan, Sean L. Stokes, Joseph P. Emerson
Format: Article
Language:English
Published: Elsevier 2021-02-01
Series:Catalysis Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736720303514