An experimental and quantumchemical study of [2+3] cycloaddition between (Z)-C-(m,m,p-trimethoxyphenyl)-N-(p-methyphenyl)-nitrone and (E)-3,3,3-trichloro-1-nitroprop-1-ene: mechanistic aspects

An experimental and quantumchemical study of [2+3] cycloaddition between (Z)-C-(m,m,p-trimethoxyphenyl)-N-(p-methyphenyl)-nitrone and (E)-3,3,3-trichloro-1-nitroprop-1-ene: mechanistic aspects

Analysis of addent interactions with respect to the theory of electrophilicity and nucleophilicity indexes and kinetic studies shows the polar nature of [2+3] cycloaddition of (Z)-C-(m,m,p-trimethoxyphenyl)-N-(p-methylphenyl)-nitrone to (E)-3,3,3-trichloro-1-nitroprop-1-ene. However, PES exploration...

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Bibliographic Details
Main Authors: Alicja Szczepanek, Ewa Jasińska, Agnieszka Kącka, Radomir Jasiński
Format: Article
Language:English
Published: Growing Science 2015-01-01
Series:Current Chemistry Letters
Subjects:
Nitrone
Nitroalkene [2+3]
Cycloaddition
Kinetic
Mechanism
DFT calculations
Online Access:http://www.growingscience.com/ccl/Vol4/ccl_2014_19.pdf

Internet

http://www.growingscience.com/ccl/Vol4/ccl_2014_19.pdf

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