Poly[octacarbonylheptakis(tetrahydrofuran)diironmanganesedisodium(2 Mn—Fe)]
The reaction of Na2Fe(CO)4 with an excess of MnCl2 in tetrahydrofuran (THF) produced {Fe2Mn(C4H8O)2Na2(C4H8O)5(CO)8]n or C36H56Fe2MnNa2O15. The compound is a xenophilic dianion with short iron–manganese bond lengths of 2.6274 (10) and 2.6294 (10) Å. The sodium cations of the dianion are coordinated...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2021-08-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314621008452 |