Infrared pre-excitation grants isotopomer-specific photochemistry

Species-selective photochemistry is often hampered by overlapping UV-Vis spectra. We overcome this long-standing problem by combined vibrational and electronic excitation as demonstrated by isotopomer selection. The influence of various factors on selectivity is discussed.

Bibliographic Details
Main Authors: Kern-Michler Daniela, Neumann Carsten, Mielke Nicole, Luuk J. G. W. van Wilderen, Reinfelds Matiss, von Cosel Jan, Santoro Fabrizio, Heckel Alexander, Burghardt Irene, Bredenbeck Jens
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:EPJ Web of Conferences
Online Access:https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_03001.pdf