Monodisperse Polymer Melts Crystallize via Structurally Polydisperse Nanoscale Clusters: Insights from Polyethylene

This study demonstrates that monodisperse entangled polymer melts crystallize via the formation of nanoscale nascent polymer crystals (i.e., nuclei) that exhibit substantial variability in terms of their constituent crystalline polymer chain segments (stems). More specifically, large-scale coarse-gr...

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Bibliographic Details
Main Authors: Kyle Wm. Hall, Timothy W. Sirk, Simona Percec, Michael L. Klein, Wataru Shinoda
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/2/447