Crystal structure of a tetranuclear CuII complex with an O,N,N′-donor Schiff base ligand: hexa-μ2-acetato-bis(2-{[(2,2,6,6-tetramethylpiperidin-4-yl)imino]methyl}phenolato-κ3O,N,N′)tetracopper(II)

Crystal structure of a tetranuclear CuII complex with an O,N,N′-donor Schiff base ligand: hexa-μ2-acetato-bis(2-{[(2,2,6,6-tetramethylpiperidin-4-yl)imino]methyl}phenolato-κ3O,N,N′)tetracopper(II)

The title compound, [Cu4(CH3COO)6(C16H23N2O)2], lies across a twofold rotation axis. The asymmetric unit contains two independent CuII ions. The symmetry-unique terminal CuII ion is O,N,N′-coordinated by a 2-{[(2,2,6,6-tetramethylpiperidin-4-yl)imino]methyl}phenolate ligand and an O atom from an ace...

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Bibliographic Details
Main Authors: Guohui Huang, Xiaoxuan Liu
Format: Article
Language:English
Published: International Union of Crystallography 2016-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
Schiff base ligand
boat conformation
piperidines
copper(II) complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016005041

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989016005041

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