Bis(1-phenylimidazole)[5,10,15,20-tetrakis(2-pivalamidophenyl)porphinato]iron(III) trifluoromethanesulfonate chlorobenzene disolvate

Bis(1-phenylimidazole)[5,10,15,20-tetrakis(2-pivalamidophenyl)porphinato]iron(III) trifluoromethanesulfonate chlorobenzene disolvate

The title complex, [Fe(C64H64N8O4)(C9H8N2)2](CF3O3S)·2C6H5Cl, has an unusual relative orientation of the two planar axial ligands [dihedral angle between the two imidazole planes = 46.55 (9)°]. The average equatorial Fe—N bond length is 1.974 (3) Å; the axial distances are 1.9628 (19) and 1.9932 (19...

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Bibliographic Details
Main Authors: Jianfeng Li, Allen G. Oliver, W. Robert Scheidt
Format: Article
Language:English
Published: International Union of Crystallography 2019-01-01
Series:IUCrData
Subjects:
crystal structure
iron(III)porphyrin
teraphenylporphyrin
bis(imidazole) complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314619000154

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http://scripts.iucr.org/cgi-bin/paper?S2414314619000154

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