Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)

Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)

The flexible ditopic ligand 3,3-bipyridine (3,3-bpy) has been reacted with a series of transition metal species (Ag+, Hg2+, cis-a2M2+ (a=NH3 or a2=en; M=Pt,Pd), trans-a2Pt2+ (a=NH3)) in an attempt to produce discrete cyclic constructs. While Ag+ gave a polymeric structure {[Ag(3,3-bpy)](ClO4) ⋅ H...

Full description

Bibliographic Details
Main Authors: Anupam Khutia, Pablo J. Sanz Miguel, Bernhard Lippert
Format: Article
Language:English
Published: Hindawi Limited 2010-01-01
Series:Bioinorganic Chemistry and Applications
Online Access:http://dx.doi.org/10.1155/2010/169054
id doaj-8da20feb00174f92ba3e5310c7ba215a
record_format Article
spelling doaj-8da20feb00174f92ba3e5310c7ba215a2020-11-25T01:55:59ZengHindawi LimitedBioinorganic Chemistry and Applications1565-36331687-479X2010-01-01201010.1155/2010/169054169054Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)Anupam Khutia0Pablo J. Sanz Miguel1Bernhard Lippert2Fakultät Chemie, Technische Universität Dortmund, 44221 Dortmund, GermanyFakultät Chemie, Technische Universität Dortmund, 44221 Dortmund, GermanyFakultät Chemie, Technische Universität Dortmund, 44221 Dortmund, GermanyThe flexible ditopic ligand 3,3-bipyridine (3,3-bpy) has been reacted with a series of transition metal species (Ag+, Hg2+, cis-a2M2+ (a=NH3 or a2=en; M=Pt,Pd), trans-a2Pt2+ (a=NH3)) in an attempt to produce discrete cyclic constructs. While Ag+ gave a polymeric structure {[Ag(3,3-bpy)](ClO4) ⋅ H2O}𝑛 (1), with all other metal entities cyclic structures were formed. Interestingly, Hg(CH3COO)2 produced a dinuclear complex [Hg(3,3-bpy)(CH3COO)2]2 ⋅ 3H2O (2), in which the two 3,3-bpy ligands adopt a cis-orientation of the coordinating pyridyl entities. With cis-(NH3)2Pt2+, a cyclic complex 4 was isolated in crystalline form which, according to HRMS, is a trimer. With trans-(NH3)2Pt2+, different species are formed according to 1H NMR spectroscopy, the nature of which was not established.http://dx.doi.org/10.1155/2010/169054
collection DOAJ
language English
format Article
sources DOAJ
author Anupam Khutia
Pablo J. Sanz Miguel
Bernhard Lippert
spellingShingle Anupam Khutia
Pablo J. Sanz Miguel
Bernhard Lippert
Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
Bioinorganic Chemistry and Applications
author_facet Anupam Khutia
Pablo J. Sanz Miguel
Bernhard Lippert
author_sort Anupam Khutia
title Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
title_short Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
title_full Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
title_fullStr Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
title_full_unstemmed Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
title_sort molecular architectures derived from metal ions and the flexible 3,3′-bipyridine ligand: unexpected dimer with hg(ii)
publisher Hindawi Limited
series Bioinorganic Chemistry and Applications
issn 1565-3633
1687-479X
publishDate 2010-01-01
description The flexible ditopic ligand 3,3-bipyridine (3,3-bpy) has been reacted with a series of transition metal species (Ag+, Hg2+, cis-a2M2+ (a=NH3 or a2=en; M=Pt,Pd), trans-a2Pt2+ (a=NH3)) in an attempt to produce discrete cyclic constructs. While Ag+ gave a polymeric structure {[Ag(3,3-bpy)](ClO4) ⋅ H2O}𝑛 (1), with all other metal entities cyclic structures were formed. Interestingly, Hg(CH3COO)2 produced a dinuclear complex [Hg(3,3-bpy)(CH3COO)2]2 ⋅ 3H2O (2), in which the two 3,3-bpy ligands adopt a cis-orientation of the coordinating pyridyl entities. With cis-(NH3)2Pt2+, a cyclic complex 4 was isolated in crystalline form which, according to HRMS, is a trimer. With trans-(NH3)2Pt2+, different species are formed according to 1H NMR spectroscopy, the nature of which was not established.
url http://dx.doi.org/10.1155/2010/169054
work_keys_str_mv AT anupamkhutia moleculararchitecturesderivedfrommetalionsandtheflexible33bipyridineligandunexpecteddimerwithhgii
AT pablojsanzmiguel moleculararchitecturesderivedfrommetalionsandtheflexible33bipyridineligandunexpecteddimerwithhgii
AT bernhardlippert moleculararchitecturesderivedfrommetalionsandtheflexible33bipyridineligandunexpecteddimerwithhgii
_version_ 1724982353806229504

Similar Items