Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)
The flexible ditopic ligand 3,3-bipyridine (3,3-bpy) has been reacted with a series of transition metal species (Ag+, Hg2+, cis-a2M2+ (a=NH3 or a2=en; M=Pt,Pd), trans-a2Pt2+ (a=NH3)) in an attempt to produce discrete cyclic constructs. While Ag+ gave a polymeric structure {[Ag(3,3-bpy)](ClO4) ⋅ H...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Hindawi Limited
2010-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2010/169054 |