ENDOR study of nitrogen hyperfine and quadrupole tensors in vanadyl porphyrins of heavy crude oil

We report the observation of pulsed electron-nuclear double resonance (ENDOR) spectrum caused by interactions of the nitrogen nuclei 14N with the unpaired electron of the paramagnetic vanadyl complexes VO2+ of vanadyl porphyrins in natural crude oil. We provide detailed experimental and theoretical...

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Bibliographic Details
Main Author: Gracheva I.N., Gafurov M.R., Mamin G.V., Biktagirov T.B., Rodionov A.A., Galukhin A.V., Orlinskii S.B.
Format: Article
Language:English
Published: Kazan Federal University 2016-11-01
Series:Magnetic Resonance in Solids
Online Access:http://mrsej.kpfu.ru/contents/2016/MRSej_16102.pdf