ENDOR study of nitrogen hyperfine and quadrupole tensors in vanadyl porphyrins of heavy crude oil
We report the observation of pulsed electron-nuclear double resonance (ENDOR) spectrum caused by interactions of the nitrogen nuclei 14N with the unpaired electron of the paramagnetic vanadyl complexes VO2+ of vanadyl porphyrins in natural crude oil. We provide detailed experimental and theoretical...
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Format: | Article |
Language: | English |
Published: |
Kazan Federal University
2016-11-01
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Series: | Magnetic Resonance in Solids |
Online Access: | http://mrsej.kpfu.ru/contents/2016/MRSej_16102.pdf |