MÉTODO ALTERNATIVO PARA A SÍNTESE E MECANISMO DE 2-(1,3-DITIANO-2-ILIDENO)-ACETONITRILA

MÉTODO ALTERNATIVO PARA A SÍNTESE E MECANISMO DE 2-(1,3-DITIANO-2-ILIDENO)-ACETONITRILA

We report an alternative method for the synthesis of 2-(1,3-dithian-2-ylidene)-acetonitrile using 3-(4-chlorophenyl)-3-oxopropanenitrile and carbon disulfide as starting materials. The methanolysis of the intermediate 3-(4-chlorophenyl)-2-(1,3-dithian-2-ylidene)-3-oxopropanenitrile occurs via three...

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Bibliographic Details
Main Authors: Marcelle S. Ferreira, José D. Figueroa-Villar
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2015-02-01
Series:Química Nova
Subjects:
2-(1,3-dithian-2-ylidene)-acetonitrile
reaction mechanism
methanolysis
molecular modeling
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422015000200233&lng=en&tlng=en

Internet

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422015000200233&lng=en&tlng=en

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