Efficient Bulky Organo-Zinc Scorpionates for the Stereoselective Production of Poly(<i>rac</i>-lactide)s

Efficient Bulky Organo-Zinc Scorpionates for the Stereoselective Production of Poly(<i>rac</i>-lactide)s

The direct reaction of the highly sterically demanding acetamidinate-based NNN′-scorpionate protioligand Hphbp<sup>t</sup>amd [Hphbp<sup>t</sup>amd = <i>N</i>,<i>N</i>′-di-p-tolylbis(3,5-di-tertbutylpyrazole-1-yl)acetamidine] with one equiv. of ZnMe<...

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Bibliographic Details
Main Authors: Marta Navarro, Andrés Garcés, Luis F. Sánchez-Barba, Felipe de la Cruz-Martínez, Juan Fernández-Baeza, Agustín Lara-Sánchez
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Polymers
Subjects:
homogenous catalysis
zinc scorpionates
<i>rac</i>-lactide
heterotactic poly(<i>rac</i>-lactide)s
Online Access:https://www.mdpi.com/2073-4360/13/14/2356

Internet

https://www.mdpi.com/2073-4360/13/14/2356

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