Crystal structure and absolute configuration of (3aR,3′aR,7aS,7′aS)-2,2,2′,2′-tetramethyl-3a,6,7,7a,3′a,6′,7′,7′a-octahydro-4,4′-bi[1,3-benzodioxolyl], obtained from a Pd-catalyzed homocoupling reaction

Crystal structure and absolute configuration of (3aR,3′aR,7aS,7′aS)-2,2,2′,2′-tetramethyl-3a,6,7,7a,3′a,6′,7′,7′a-octahydro-4,4′-bi[1,3-benzodioxolyl], obtained from a Pd-catalyzed homocoupling reaction

The absolute configuration, i.e. (3aR,3′aR,7aS,7′aS), of the title compound, C18H26O4, synthesized via a palladium-catalyzed homocoupling reaction, was determined on the basis of the synthetic pathway and was confirmed by X-ray diffraction. The homocoupled molecule is formed by two chemically identi...

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Bibliographic Details
Main Authors: Mario A. Macías, Enrique Pandolfi, Valeria Schapiro, Gustavo P. Silveira, Guilherme D. Vilela, Leopoldo Suescun
Format: Article
Language:English
Published: International Union of Crystallography 2017-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
absolute configuration
homocoupling reaction
palladium-catalyzed
1,3-benzodioxolyl
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016019927

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http://scripts.iucr.org/cgi-bin/paper?S2056989016019927

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