Field-Induced Dysprosium Single-Molecule Magnet Based on a Redox-Active Fused 1,10-Phenanthroline-Tetrathiafulvalene-1,10-Phenanthroline Bridging Triad

Field-Induced Dysprosium Single-Molecule Magnet Based on a Redox-Active Fused 1,10-Phenanthroline-Tetrathiafulvalene-1,10-Phenanthroline Bridging Triad

Tetrathiafulvalene and 1,10-phenanthroline moieties present, respectively remarkable redox-active and complexation activities. In this work, we investigated the coordination reaction between the bis(1,10-phenanthro[5,6-b])tetrathiafulvalene triad (L) and the Dy(hfac)3·2H2O metallo precursor. The res...

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Bibliographic Details
Main Authors: Bertrand Lefeuvre, Olivier Galangau, Jessica Flores Gonzalez, Vincent Montigaud, Vincent Dorcet, Lahcène Ouahab, Boris Le Guennic, Olivier Cador, Fabrice Pointillart
Format: Article
Language:English
Published: Frontiers Media S.A. 2018-11-01
Series:Frontiers in Chemistry
Subjects:
tetrathiafulvalene
triads
dysprosium
single-molecule magnet
ab initio calculations
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2018.00552/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2018.00552/full

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