Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside

Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside

Methyl 5-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-β-L-gulofuranoside was prepared in high yield from methyl 6-deoxy-2,3-O-isopropylidene-α-D-lyxopentodialdo-1,4-furanoside. The configuration at the C5 atom was unambiguosly established by single crystal X-ray analysis of the corresponding...

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Bibliographic Details
Main Authors: Dalma Gyepesová, Vratislav Langer, Ján GajdoÅ¡, Miroslav Koóš, Bohumil Steiner, Júlia MiÄÂová
Format: Article
Language:English
Published: MDPI AG 2002-05-01
Series:Molecules
Subjects:
Saccharide cyanohydrins
methyl 2
3-O-isopropylidene-β-L-gulofuranoside
Xray crystallography
conformation
Online Access:http://www.mdpi.com/1420-3049/7/5/437/

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http://www.mdpi.com/1420-3049/7/5/437/

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