Protonation site for anilines in aqueous media

By means of the PM3 method it has been shown that the protonation of 2-, 3-, 4-methoxyanilines, 4-methylthioaniline, 2-, 3-, 4-aminobenzoic acids, 2-, 3-, 4-nitroanilines in the gaseous phase proceeds via the amine nitrogen atom. The same result, attributed to the aqueous medium, was obtained for 4-...

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Bibliographic Details
Main Authors: INNA M. UCHAEVA, ALEXEI N. PANKRATOV
Format: Article
Language:English
Published: Serbian Chemical Society 2002-02-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol67/No2/V67-No2-06.pdf