Metal-centred azaphosphatriptycene gear with a photo- and thermally driven mechanical switching function based on coordination isomerism

In metal-based molecular motors, the motion is generally triggered by changes in the ligand coordination around the metal centre. Here, the authors synthesize a molecular gear that switches between states through photo- and thermally driven geometrical isomerization around a platinum ion.

Bibliographic Details
Main Authors: Hitoshi Ube, Yoshihiro Yasuda, Hiroyasu Sato, Mitsuhiko Shionoya
Format: Article
Language:English
Published: Nature Publishing Group 2017-02-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms14296