Photochemical and Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime

Photochemical and Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime

Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime (4) (prepared in 4 steps starting from cholest-5-en-3b-ol (1)) with thionyl chloride in dioxane solution afforded an enamide-type lactam, i.e., 7-aza-B-homocholest-4-en-6-one (6) as a single product. Photoreaction of the same compound in methano...

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Bibliographic Details
Main Authors: VLADIMIR D. PAVLOVIC, LJUBINKA B. LORENC, MILAN M. DABOVIC, MIRA S. BJELAKOVIC, NATALIJA M. KRSTIC
Format: Article
Language:English
Published: Serbian Chemical Society 2004-06-01
Series:Journal of the Serbian Chemical Society
Subjects:
(Z)-cholest-4-en-6-one oxime
7-aza-B-homocholest-4-en-6-one
Beckmann rearrangement
photoreaction
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol69/No6/V69-No6-01.pdf

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http://www.shd.org.yu/HtDocs/SHD/Vol69/No6/V69-No6-01.pdf

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