Synthesis, crystal structure and catalytic activity in reductive amination of dichlorido(η6-p-cymene)(2′-dicyclohexylphosphanyl-2,6-dimethoxybiphenyl-κP)ruthenium(II)

Synthesis, crystal structure and catalytic activity in reductive amination of dichlorido(η6-p-cymene)(2′-dicyclohexylphosphanyl-2,6-dimethoxybiphenyl-κP)ruthenium(II)

The title compound, [RuCl2(C10H14)(C26H35O2P)] (I), crystallizes in the monoclinic space group P21/c with two crystallographically independent molecules (A and B) in the asymmetric unit. The geometries of both molecules are very similar and distinguished only by the twist angles of the two benzene r...

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Bibliographic Details
Main Authors: Maria Makarova, Alexey A. Tsygankov, Olga Chusova, Ivan V. Linko, Pavel V. Dorovatovskii, Yan V. Zubavichus
Format: Article
Language:English
Published: International Union of Crystallography 2018-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
ruthenium(II)
η6-arene complex
phosphine complex
reductive amination
carbon monoxide
synchrotron radiation
hydrogen bonding
C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018003821

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http://scripts.iucr.org/cgi-bin/paper?S2056989018003821

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