KPFM surface photovoltage measurement and numerical simulation

• Main Authors: Marchat Clément, Connolly James P., Kleider Jean-Paul, Alvarez José, Koduvelikulathu Lejo J., Puel Jean Baptiste
• Format: Article
• Language: English
• Published: EDP Sciences 2019-01-01
• Series: EPJ Photovoltaics
• Subjects: kpfm; spv; surface defects; modeling and band bending
• Online Access: https://www.epj-pv.org/articles/epjpv/full_html/2019/01/pv180014/pv180014.html

A method for the analysis of Kelvin probe force microscopy (KPFM) characterization of semiconductor devices is presented. It enables evaluation of the influence of defective surface layers. The model is validated by analysing experimental KPFM measurements on crystalline silicon samples of contact potential difference (VCPD) in the dark and under illumination, and hence the surface photovoltage (SPV). It is shown that the model phenomenologically explains the observed KPFM measurements. It reproduces the magnitude of SPV characterization as a function of incident light power in terms of a defect density assuming Gaussian defect distribution in the semiconductor bandgap. This allows an estimation of defect densities in surface layers of semiconductors and therefore increased exploitation of KPFM data.