On the mechanism of imine elimination from Fischer tungsten carbene complexes

On the mechanism of imine elimination from Fischer tungsten carbene complexes

(Aminoferrocenyl)(ferrocenyl)carbene(pentacarbonyl)tungsten(0) (CO)5W=C(NHFc)Fc (W(CO)5(E-2)) is synthesized by nucleophilic substitution of the ethoxy group of (CO)5W=C(OEt)Fc (M(CO)5(1Et)) by ferrocenyl amide Fc-NH– (Fc = ferrocenyl). W(CO)5(E-2) thermally and photochemically eliminates bulky E-1,...

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Bibliographic Details
Main Authors: Philipp Veit, Christoph Förster, Katja Heinze
Format: Article
Language:English
Published: Beilstein-Institut 2016-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
carbene complexes
ferrocene
imine
mechanism
tungsten
Online Access:https://doi.org/10.3762/bjoc.12.125

Internet

https://doi.org/10.3762/bjoc.12.125

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