Clicking Azides and Alkynes with Poly(pyrazolyl)borate-Copper(I) Catalysts: An Experimental and Computational Study

Clicking Azides and Alkynes with Poly(pyrazolyl)borate-Copper(I) Catalysts: An Experimental and Computational Study

The synthesis of 1,4-disubstituted-1,2,3-triazoles under a copper(I)-catalyzed azide&#8722;alkyne cycloaddition (CuAAC) regime was accomplished in high yields and a regioselective manner by using two homoscorpionate poly(pyrazolyl)borate anions: tris(pyrazolyl)hydroborate (HB(pz)<sub>3<...

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Bibliographic Details
Main Authors: Lahoucine Bahsis, Hicham Ben El Ayouchia, Hafid Anane, Carmen Ramirez de Arellano, Abdeslem Bentama, El Mestafa El Hadrami, Miguel Julve, Luis R. Domingo, Salah-Eddine Stiriba
Format: Article
Language:English
Published: MDPI AG 2019-08-01
Series:Catalysts
Subjects:
click chemistry
azides
alkynes
copper(I)
poly(pyrazolyl)borate
1,2,3-triazole
DFT calculations
Online Access:https://www.mdpi.com/2073-4344/9/8/687

Internet

https://www.mdpi.com/2073-4344/9/8/687

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