Hypervalent iodine compounds for anti-Markovnikov-type iodo-oxyimidation of vinylarenes

Hypervalent iodine compounds for anti-Markovnikov-type iodo-oxyimidation of vinylarenes

The iodo-oxyimidation of styrenes with the N-hydroxyimide/I2/hypervalent iodine oxidant system was proposed. Among the examined hypervalent iodine oxidants (PIDA, PIFA, IBX, DMP) PhI(OAc)2 proved to be the most effective; yields of iodo-oxyimides are 34–91%. A plausible reaction pathway includes the...

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Bibliographic Details
Main Authors: Igor B. Krylov, Stanislav A. Paveliev, Mikhail A. Syroeshkin, Alexander A. Korlyukov, Pavel V. Dorovatovskii, Yan V. Zubavichus, Gennady I. Nikishin, Alexander O. Terent’ev
Format: Article
Language:English
Published: Beilstein-Institut 2018-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
free radicals
hypervalent iodine
imide-N-oxyl radicals
iodination
N-hydroxyimides
oxidative functionalization
Online Access:https://doi.org/10.3762/bjoc.14.188

Internet

https://doi.org/10.3762/bjoc.14.188

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