Heterogeneous Asymmetric Oxidation Catalysis Using Hemophore HasApf. Application in the Chemoenzymatic Deracemization of sec-Alcohols with Sodium Borohydride

Heterogeneous Asymmetric Oxidation Catalysis Using Hemophore HasApf. Application in the Chemoenzymatic Deracemization of sec-Alcohols with Sodium Borohydride

This study aims to demonstrate the coordination of oxygen regarding the hemophore HasApf expressed by Escherichia coli cells, which appears to create an unlikely oxygen-activating system in HasA due to the already-coordinated iron. In the asymmetric oxidation of rac-1-(6-methoxynaphthalen-2-yl)ethan...

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Bibliographic Details
Main Author: Hiroyuki Nagaoka
Format: Article
Language:English
Published: MDPI AG 2016-03-01
Series:Catalysts
Subjects:
enantioselective oxidation
hemophore HasA
heterogeneous enzyme catalysis
iron electron-transfer system
iron porphyrin
Online Access:http://www.mdpi.com/2073-4344/6/3/38

Internet

http://www.mdpi.com/2073-4344/6/3/38

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