The preferred conformation of erythro- and threo-1,2-difluorocyclododecanes

The preferred conformation of erythro- and threo-1,2-difluorocyclododecanes

Cyclododecane adopts a square-like structure with corner and edge CH2 groups. In this study erythro- and threo-1,2-difluorocyclododecanes were prepared to explore whether the two vicinal C–F bonds, with different relative configurations, preferably locate at corner/edge or edge/edge locations. Confo...

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Bibliographic Details
Main Authors: Yi Wang, Peer Kirsch, Tomas Lebl, Alexandra M. Z. Slawin, David O'Hagan
Format: Article
Language:English
Published: Beilstein-Institut 2012-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
alicyclic chemistry
conformational analysis
cyclododecane
19F NMR
organo-fluorine chemistry
transannular interactions
Online Access:https://doi.org/10.3762/bjoc.8.143

Internet

https://doi.org/10.3762/bjoc.8.143

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