Crystal Structure of Na3MoCl6

The ternary chloride Na3MoCl6 is obtained as red crystals from a disproportionation reaction of molybdenum dichloride, {Mo6}Cl12, in an acidic NaCl/AlCl3 melt at 350 °C. The crystal structure (trigonal, P-31c, a = 687.1(1), c = 1225.3(2) pm, Z = 2, V = 501,0(1) 106 pm3) is that of Na3CrCl6: within a...

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Bibliographic Details
Main Authors: Martin Beran, Gerd Meyer
Format: Article
Language:English
Published: MDPI AG 2011-07-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/1/3/99