V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>

Vanadium pentoxide thin films were deposited onto insulating support by means of rf reactive sputtering from a metallic vanadium target. Argon-oxygen gas mixtures of different compositions controlled by the flow rates were used for sputtering. X-ray diffraction at glancing incidence (GIXD) and Scann...

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Main Authors: Krystyna Schneider, Wojciech Maziarz
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/18/12/4177
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spelling doaj-7b082dad49aa4726a277c84dea2bbc9f2020-11-24T22:58:24ZengMDPI AGSensors1424-82202018-11-011812417710.3390/s18124177s18124177V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>Krystyna Schneider0Wojciech Maziarz1AGH University of Science and Technology, Faculty of Computer Science, Electronics and Telecommunications, Department of Electronics, 30-059 Krakow, PolandAGH University of Science and Technology, Faculty of Computer Science, Electronics and Telecommunications, Department of Electronics, 30-059 Krakow, PolandVanadium pentoxide thin films were deposited onto insulating support by means of rf reactive sputtering from a metallic vanadium target. Argon-oxygen gas mixtures of different compositions controlled by the flow rates were used for sputtering. X-ray diffraction at glancing incidence (GIXD) and Scanning Electronic Microscopy (SEM) were used for structural and phase characterization. Thickness of the films was determined by the profilometry. It has been confirmed by GIXD that the deposited films are composed of V<sub>2</sub>O<sub>5</sub> phase. The gas sensing properties of V<sub>2</sub>O<sub>5</sub> thin films were investigated at temperatures from range 410&#8315;617 K upon NO<sub>2</sub> gas of 4&#8315;20 ppm. The investigated material exhibited good response and reversibility towards nitrogen dioxide. The effect of metal-insulator transition (MIT) on sensor performance has been observed and discussed for the first time. It was found that a considerable increase of the sensor sensitivity occured above 545 K, which is related to postulated metal-insulator transition.https://www.mdpi.com/1424-8220/18/12/4177vanadium pentoxidethin filmreactive sputteringelectrical propertiesnitrogen dioxidegas sensormetal-insulator transition (MIT)
collection DOAJ
language English
format Article
sources DOAJ
author Krystyna Schneider
Wojciech Maziarz
spellingShingle Krystyna Schneider
Wojciech Maziarz
V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
Sensors
vanadium pentoxide
thin film
reactive sputtering
electrical properties
nitrogen dioxide
gas sensor
metal-insulator transition (MIT)
author_facet Krystyna Schneider
Wojciech Maziarz
author_sort Krystyna Schneider
title V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
title_short V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
title_full V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
title_fullStr V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
title_full_unstemmed V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
title_sort v<sub>2</sub>o<sub>5</sub> thin films as nitrogen dioxide sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
publisher MDPI AG
series Sensors
issn 1424-8220
publishDate 2018-11-01
description Vanadium pentoxide thin films were deposited onto insulating support by means of rf reactive sputtering from a metallic vanadium target. Argon-oxygen gas mixtures of different compositions controlled by the flow rates were used for sputtering. X-ray diffraction at glancing incidence (GIXD) and Scanning Electronic Microscopy (SEM) were used for structural and phase characterization. Thickness of the films was determined by the profilometry. It has been confirmed by GIXD that the deposited films are composed of V<sub>2</sub>O<sub>5</sub> phase. The gas sensing properties of V<sub>2</sub>O<sub>5</sub> thin films were investigated at temperatures from range 410&#8315;617 K upon NO<sub>2</sub> gas of 4&#8315;20 ppm. The investigated material exhibited good response and reversibility towards nitrogen dioxide. The effect of metal-insulator transition (MIT) on sensor performance has been observed and discussed for the first time. It was found that a considerable increase of the sensor sensitivity occured above 545 K, which is related to postulated metal-insulator transition.
topic vanadium pentoxide
thin film
reactive sputtering
electrical properties
nitrogen dioxide
gas sensor
metal-insulator transition (MIT)
url https://www.mdpi.com/1424-8220/18/12/4177
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