V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>
Vanadium pentoxide thin films were deposited onto insulating support by means of rf reactive sputtering from a metallic vanadium target. Argon-oxygen gas mixtures of different compositions controlled by the flow rates were used for sputtering. X-ray diffraction at glancing incidence (GIXD) and Scann...
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doaj-7b082dad49aa4726a277c84dea2bbc9f2020-11-24T22:58:24ZengMDPI AGSensors1424-82202018-11-011812417710.3390/s18124177s18124177V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref>Krystyna Schneider0Wojciech Maziarz1AGH University of Science and Technology, Faculty of Computer Science, Electronics and Telecommunications, Department of Electronics, 30-059 Krakow, PolandAGH University of Science and Technology, Faculty of Computer Science, Electronics and Telecommunications, Department of Electronics, 30-059 Krakow, PolandVanadium pentoxide thin films were deposited onto insulating support by means of rf reactive sputtering from a metallic vanadium target. Argon-oxygen gas mixtures of different compositions controlled by the flow rates were used for sputtering. X-ray diffraction at glancing incidence (GIXD) and Scanning Electronic Microscopy (SEM) were used for structural and phase characterization. Thickness of the films was determined by the profilometry. It has been confirmed by GIXD that the deposited films are composed of V<sub>2</sub>O<sub>5</sub> phase. The gas sensing properties of V<sub>2</sub>O<sub>5</sub> thin films were investigated at temperatures from range 410⁻617 K upon NO<sub>2</sub> gas of 4⁻20 ppm. The investigated material exhibited good response and reversibility towards nitrogen dioxide. The effect of metal-insulator transition (MIT) on sensor performance has been observed and discussed for the first time. It was found that a considerable increase of the sensor sensitivity occured above 545 K, which is related to postulated metal-insulator transition.https://www.mdpi.com/1424-8220/18/12/4177vanadium pentoxidethin filmreactive sputteringelectrical propertiesnitrogen dioxidegas sensormetal-insulator transition (MIT) |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Krystyna Schneider Wojciech Maziarz |
spellingShingle |
Krystyna Schneider Wojciech Maziarz V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref> Sensors vanadium pentoxide thin film reactive sputtering electrical properties nitrogen dioxide gas sensor metal-insulator transition (MIT) |
author_facet |
Krystyna Schneider Wojciech Maziarz |
author_sort |
Krystyna Schneider |
title |
V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref> |
title_short |
V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref> |
title_full |
V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref> |
title_fullStr |
V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref> |
title_full_unstemmed |
V<sub>2</sub>O<sub>5</sub> Thin Films as Nitrogen Dioxide Sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref> |
title_sort |
v<sub>2</sub>o<sub>5</sub> thin films as nitrogen dioxide sensors <xref rid="fn1-sensors-375730" ref-type="fn">†</xref> |
publisher |
MDPI AG |
series |
Sensors |
issn |
1424-8220 |
publishDate |
2018-11-01 |
description |
Vanadium pentoxide thin films were deposited onto insulating support by means of rf reactive sputtering from a metallic vanadium target. Argon-oxygen gas mixtures of different compositions controlled by the flow rates were used for sputtering. X-ray diffraction at glancing incidence (GIXD) and Scanning Electronic Microscopy (SEM) were used for structural and phase characterization. Thickness of the films was determined by the profilometry. It has been confirmed by GIXD that the deposited films are composed of V<sub>2</sub>O<sub>5</sub> phase. The gas sensing properties of V<sub>2</sub>O<sub>5</sub> thin films were investigated at temperatures from range 410⁻617 K upon NO<sub>2</sub> gas of 4⁻20 ppm. The investigated material exhibited good response and reversibility towards nitrogen dioxide. The effect of metal-insulator transition (MIT) on sensor performance has been observed and discussed for the first time. It was found that a considerable increase of the sensor sensitivity occured above 545 K, which is related to postulated metal-insulator transition. |
topic |
vanadium pentoxide thin film reactive sputtering electrical properties nitrogen dioxide gas sensor metal-insulator transition (MIT) |
url |
https://www.mdpi.com/1424-8220/18/12/4177 |
work_keys_str_mv |
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1725647297321107456 |