Stereoselective Formation of Substituted 1,3-Dioxolanes through a Three-Component Assembly during the Oxidation of Alkenes with Hypervalent Iodine(III)

Stereoselective Formation of Substituted 1,3-Dioxolanes through a Three-Component Assembly during the Oxidation of Alkenes with Hypervalent Iodine(III)

Stereoselective formation of substituted 1,3-dioxolanes was achieved through an assembly of three components: alkene, carboxylic acid and silyl enol ether. The reaction proceeded via stereospecific generation of a 1,3-dioxolan-2-yl cation intermediate during oxidation of alkene substrates with hyper...

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Bibliographic Details
Main Authors: Mio Shimogaki, Morifumi Fujita, Takashi Sugimura
Format: Article
Language:English
Published: MDPI AG 2015-09-01
Series:Molecules
Subjects:
hypervalent iodine
oxidation
dioxolane
dioxolanyl cation
stereoselective synthesis
Online Access:http://www.mdpi.com/1420-3049/20/9/17041

Internet

http://www.mdpi.com/1420-3049/20/9/17041

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