Transition-Metal-Catalyzed Diarylation of Isocyanides with Triarylbismuthines for the Selective Synthesis of Imine Derivatives

Transition-Metal-Catalyzed Diarylation of Isocyanides with Triarylbismuthines for the Selective Synthesis of Imine Derivatives

The transition-metal-catalyzed diarylation of isocyanides with triarylbismuthines was investigated in detail, and rhodium catalysts such as [RhCl(nbd)]<sub>2</sub> were found to selectively afford <i>N</i>-alkyl diaryl ketimines. On the other hand, palladium-catalyzed diaryla...

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Bibliographic Details
Main Authors: Shintaro Kodama, Yuki Yamamoto, Yohsuke Kobiki, Hitomi Matsubara, Cong Chi Tran, Shin-ichi Kawaguchi, Akihiro Nomoto, Akiya Ogawa
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Materials
Subjects:
arylation
isocyanide
imine
triarylbismuthine
2,3-diarylquinoxaline
Online Access:https://www.mdpi.com/1996-1944/14/15/4271

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https://www.mdpi.com/1996-1944/14/15/4271

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