Toward Single Atom Chains with Exfoliated Tellurium

Abstract We demonstrate that the atom chain structure of Te allows it to be exfoliated as ultra-thin flakes and nanowires. Atomic force microscopy of exfoliated Te shows that thicknesses of 1–2 nm and widths below 100 nm can be exfoliated with this method. The Raman modes of exfoliated Te match thos...

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Main Authors: Hugh O. H. Churchill, Gregory J. Salamo, Shui-Qing Yu, Takayuki Hironaka, Xian Hu, Jeb Stacy, Ishiang Shih
Format: Article
Language:English
Published: SpringerOpen 2017-08-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://link.springer.com/article/10.1186/s11671-017-2255-x
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spelling doaj-77d43c2ac2c247d58a50e1a3f595ce6e2020-11-24T21:53:00ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2017-08-011211610.1186/s11671-017-2255-xToward Single Atom Chains with Exfoliated TelluriumHugh O. H. Churchill0Gregory J. Salamo1Shui-Qing Yu2Takayuki Hironaka3Xian Hu4Jeb Stacy5Ishiang Shih6Department of Physics, University of ArkansasDepartment of Physics, University of ArkansasInstitute for Nanoscience and Engineering, University of ArkansasInstitute for Nanoscience and Engineering, University of ArkansasDepartment of Physics, University of ArkansasDepartment of Physics, University of ArkansasDepartment of Electrical and Computer Engineering, McGill UniversityAbstract We demonstrate that the atom chain structure of Te allows it to be exfoliated as ultra-thin flakes and nanowires. Atomic force microscopy of exfoliated Te shows that thicknesses of 1–2 nm and widths below 100 nm can be exfoliated with this method. The Raman modes of exfoliated Te match those of bulk Te, with a slight shift (4 cm−1) due to a hardening of the A1 and E modes. Polarized Raman spectroscopy is used to determine the crystal orientation of exfoliated Te flakes. These experiments establish exfoliation as a route to achieve nanoscale trigonal Te while also demonstrating the potential for fabrication of single atom chains of Te.http://link.springer.com/article/10.1186/s11671-017-2255-xAtom chainTelluriumExfoliation1D layered material
collection DOAJ
language English
format Article
sources DOAJ
author Hugh O. H. Churchill
Gregory J. Salamo
Shui-Qing Yu
Takayuki Hironaka
Xian Hu
Jeb Stacy
Ishiang Shih
spellingShingle Hugh O. H. Churchill
Gregory J. Salamo
Shui-Qing Yu
Takayuki Hironaka
Xian Hu
Jeb Stacy
Ishiang Shih
Toward Single Atom Chains with Exfoliated Tellurium
Nanoscale Research Letters
Atom chain
Tellurium
Exfoliation
1D layered material
author_facet Hugh O. H. Churchill
Gregory J. Salamo
Shui-Qing Yu
Takayuki Hironaka
Xian Hu
Jeb Stacy
Ishiang Shih
author_sort Hugh O. H. Churchill
title Toward Single Atom Chains with Exfoliated Tellurium
title_short Toward Single Atom Chains with Exfoliated Tellurium
title_full Toward Single Atom Chains with Exfoliated Tellurium
title_fullStr Toward Single Atom Chains with Exfoliated Tellurium
title_full_unstemmed Toward Single Atom Chains with Exfoliated Tellurium
title_sort toward single atom chains with exfoliated tellurium
publisher SpringerOpen
series Nanoscale Research Letters
issn 1931-7573
1556-276X
publishDate 2017-08-01
description Abstract We demonstrate that the atom chain structure of Te allows it to be exfoliated as ultra-thin flakes and nanowires. Atomic force microscopy of exfoliated Te shows that thicknesses of 1–2 nm and widths below 100 nm can be exfoliated with this method. The Raman modes of exfoliated Te match those of bulk Te, with a slight shift (4 cm−1) due to a hardening of the A1 and E modes. Polarized Raman spectroscopy is used to determine the crystal orientation of exfoliated Te flakes. These experiments establish exfoliation as a route to achieve nanoscale trigonal Te while also demonstrating the potential for fabrication of single atom chains of Te.
topic Atom chain
Tellurium
Exfoliation
1D layered material
url http://link.springer.com/article/10.1186/s11671-017-2255-x
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AT xianhu towardsingleatomchainswithexfoliatedtellurium
AT jebstacy towardsingleatomchainswithexfoliatedtellurium
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