On the Reaction of 1,3-Diphenylisobenzofuran and (2-Iodoethynyl)(phenyl)iodonium Triflate. A Unique Case of Oxygen Transfer from the Diels-Alder Adduct to the Diene

On the Reaction of 1,3-Diphenylisobenzofuran and (2-Iodoethynyl)(phenyl)iodonium Triflate. A Unique Case of Oxygen Transfer from the Diels-Alder Adduct to the Diene

Reaction of 1,3-diphenylisobenzofuran (DPIBF) with 2-(iodoethynyl)(phenyl)-iodonium triflate at room temperature gave the expected Diels-Alder adduct, but using an excess of DFIBF (2 equiv.) and performing the reaction at 55 °C or heating at this temperature during the concentration stage, the initi...

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Bibliographic Details
Main Authors: Mercè Font-Bardia, Teresa Calvet, David Lozano, Pelayo Camps, Tània Gómez
Format: Article
Language:English
Published: MDPI AG 2012-07-01
Series:Molecules
Subjects:
NMR spectroscopy
structure elucidation
X-ray diffraction
Online Access:http://www.mdpi.com/1420-3049/17/8/8795

Internet

http://www.mdpi.com/1420-3049/17/8/8795

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