Distinct coordination geometries in bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]diphenyltin(IV) and bis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2S,S′]diphenyltin(IV): crystal structures and Hirshfeld surface analysis

Distinct coordination geometries in bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]diphenyltin(IV) and bis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2S,S′]diphenyltin(IV): crystal structures and Hirshfeld surface analysis

The crystal and molecular structures of two diphenyltin bis(dithiocarbamate)s, [Sn(C6H5)2(C5H10NOS2)2], (I), and [Sn(C6H5)2(C7H14NO2S2)2], (II), are described. In (I), in which the metal atom lies on a twofold rotation axis, the dithiocarbamate ligand coordinates with approximately equal Sn—S bond l...

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Bibliographic Details
Main Authors: Rapidah Mohamad, Normah Awang, Mukesh M. Jotani, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2016-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
organotin
dithiocarbamate
Hirshfeld surface analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016011385

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http://scripts.iucr.org/cgi-bin/paper?S2056989016011385

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