Symmetric Assembly of a Sterically Encumbered Allyl Complex: Mechanochemical and Solution Synthesis of the Tris(allyl)beryllate, K[BeA′3] (A′ = 1,3-(SiMe3)2C3H3)

Symmetric Assembly of a Sterically Encumbered Allyl Complex: Mechanochemical and Solution Synthesis of the Tris(allyl)beryllate, K[BeA′3] (A′ = 1,3-(SiMe3)2C3H3)

The ball milling of beryllium chloride with two equivalents of the potassium salt of bis(1,3-trimethylsilyl)allyl anion, K[A′] (A′ = [1,3-(SiMe3)2C3H3]), produces the tris(allyl)beryllate K[BeA’3] (1) rather than the expected neutral BeA’2. The same product is obtained from reaction in hexanes; in c...

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Bibliographic Details
Main Authors: Nicholas C. Boyde, Nicholas R. Rightmire, Timothy P. Hanusa, William W. Brennessel
Format: Article
Language:English
Published: MDPI AG 2017-05-01
Series:Inorganics
Subjects:
allyl ligands
beryllium
coordination modes
mechanochemistry
X-ray diffraction
density functional theory calculations
Online Access:http://www.mdpi.com/2304-6740/5/2/36

Internet

http://www.mdpi.com/2304-6740/5/2/36

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