Synthesis and chemical behaviour of 17a-butyl-3b,17b-dihydroxy-16-oximino-5-androstene (NOTE)

Starting from 3b-hydroxy-16-oximino-5-androsten-17-one (1), the recently synthesized 16-oximino-17b-hydroxy-17a-butyl derivative 2 gave by the Beckmann fragmentation reaction with titanium(III) chloride or p-toluenesulphonyl chloride the corresponding D-seco derivative 3. However, using acetic anhyd...

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Bibliographic Details
Main Authors: KATARINA PENOV GASI, MARIJA SAKAC, LJUBICA MEDIC-MIJACEVIC, DORA MOLNÁR GÁBOR, SRDJAN STOJANOVIC
Format: Article
Language:English
Published: Serbian Chemical Society 2001-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol66/No1/V66-no1-04.pdf